As of tonight's NXT tapings, we seem to have the full card in place for TakeOver: Phoenix. Spoilers lay ahead because this is based on episodes that haven't aired yet:

NXT Heavyweight Title Match
Tommaso Ciampa vs. Aleister Black

NXT North American Title Match
Ricochet vs. Johnny Gargano

NXT Women's Title Match
Shayna Baszler vs. Bianca Belair

NXT Tag Team Title Match
The Undisputed Era vs. The War Raiders

We could also see Velveteen Dream vs. Adam Cole and/or Matt Riddle vs. Kassius Ohno.